| DATE | HOME | SCORE | AWAY | |||
|---|---|---|---|---|---|---|
| 21/10/2000 |  | BARCELONA | 2 - 0 | REAL MADRID |  | |
| 21/10/2000 |  | DEPORTIVO LA CORUÑA | 1 - 1 | MALLORCA |  | |
| 21/10/2000 |  | VALENCIA | 1 - 0 | REAL ZARAGOZA |  | |
| 22/10/2000 |  | ATHLETIC BILBAO | 0 - 3 | LAS PALMAS |  | |
| 22/10/2000 |  | DEPORTIVO ALAVÉS | 1 - 0 | ESPANYOL |  | |
| 22/10/2000 |  | MÁLAGA | 2 - 1 | VILLARREAL |  | |
| 22/10/2000 |  | RACING SANTANDER | 4 - 2 | NUMANCIA |  | |
| 22/10/2000 |  | RAYO VALLECANO | 4 - 1 | REAL SOCIEDAD |  | |
| 22/10/2000 |  | REAL OVIEDO | 3 - 1 | CELTA DE VIGO |  | |
| 22/10/2000 |  | REAL VALLADOLID | 1 - 1 | OSASUNA |  |
