| DATE | HOME | SCORE | AWAY | ||||
| 18.09.2004 |  | OSASUNA | 3-2 | REAL BETIS |  | ||
| 18.09.2004 |  | ESPANYOL | 1-0 | REAL MADRID |  | ||
| 18.09.2004 |  | VALENCIA | 3-1 | REAL SOCIEDAD |  | ||
| 19.09.2004 |  | ATHLETIC BILBAO | 1-2 | DEPORTIVO LA CORUÑA |  | ||
| 19.09.2004 |  | NUMANCIA | 1-0 | GETAFE |  | ||
| 19.09.2004 |  | MALLORCA | 1-2 | MÁLAGA |  | ||
| 19.09.2004 |  | REAL ZARAGOZA | 4-3 | ALBACETE |  | ||
| 19.09.2004 |  | ATLÉTICO MADRID | 1-1 | BARCELONA |  | ||
| 19.09.2004 |  | SEVILLA | 3-0 | LEVANTE |  | ||
| 19.09.2004 |  | RACING SANTANDER | 1-1 | VILLARREAL |  |
