| DATE | HOME | SCORE | AWAY | ||||
| 27.08.2005 |  | DEPORTIVO ALAVÉS | 0-0 | BARCELONA |  | ||
| 27.08.2005 |  | VALENCIA | 1-0 | REAL BETIS |  | ||
| 27.08.2005 |  | ATHLETIC BILBAO | 3-0 | REAL SOCIEDAD |  | ||
| 28.08.2005 |  | SEVILLA | 1-0 | RACING SANTANDER |  | ||
| 28.08.2005 |  | CÁDIZ | 1-2 | REAL MADRID |  | ||
| 28.08.2005 |  | CELTA DE VIGO | 2-0 | MÁLAGA |  | ||
| 28.08.2005 |  | ESPANYOL | 0-2 | GETAFE |  | ||
| 28.08.2005 |  | MALLORCA | 0-1 | DEPORTIVO LA CORUÑA |  | ||
| 28.08.2005 |  | ATLÉTICO MADRID | 0-0 | REAL ZARAGOZA |  | ||
| 28.08.2005 |  | OSASUNA | 2-1 | VILLARREAL |  |
